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Thermodynamics

Thermodynamics is the branch of physics and chemistry that studies heat, work, temperature, and energy transfer between macroscopic systems.

Type: Field Domain: Physics Chemistry Era: 1824 — 1870

Overview

The zeroth law makes thermal equilibrium transitive. For a closed system with unchanged bulk kinetic and potential energies, the first law gives ΔU = Q − W, with Q the heat entering and W the work done by the system. The second law requires the entropy of an isolated macroscopic system not to decrease. In the third law’s ideal limit, a pure perfect crystal with a unique ground state has entropy approaching zero as its temperature approaches 0 K.

Why it matters

Thermodynamics supplies cycle limits and criteria for chemical change. Carnot analysis relates an ideal heat engine’s efficiency to reservoir temperatures; Gibbs energy evaluates a thermodynamic direction under specified constraints. Such bounds and criteria do not by themselves determine an actual machine’s power or the speed of a reaction.

Where it leads

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